Product ID:76 DIESEL #2 LS
MSDS Date:12/27/1993
FSC:9140
NIIN:00-000-0184
MSDS Number: BTVWC

UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV

1201 W 5TH ST
LOS ANGELES, CA 90060
US

Emergency Phone: 800-424-9300(CHEMTREC)/800-356-3129

Info Phone: 213-977-7589/

Cage: 23034

76 PRODUCTS CO

LOS ANGELES, CA 90017 US

Telephone: 213-977-7589

Cage: 23034

PETROLEUM MID-DISTILLATE (DIESEL FUEL NO. 2)

CAS: 68476-34-6

Fraction By Weight: >99.5%

NAPHTHALENE (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: <0.5%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PETROLEUM DISTILLATES (NAPHTHA).

Fraction By Weight: N/GIVEN

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MILD EYE IRRIT. SEVERE SKIN IRRIT.HO
HARMFUL EFFECTS FROM SKIN ABSORPTION HAVE BEEN REPORTED. INHAL:NO
IFO AVAILABLE. INGEST:LOW DEGREE OF TOXICITY. ASPIRATION HAZ
CAUSING LUNG INFLAMM & DAMAGE.
Explanation of Carcinogenicity:PER MSDS POSSIBLE HUMAN CANCER
HAZ.CHRONIC DERM TESTS ON MICE SHOWED SKIN TUMORS.NTP-NAPHTHALENE
CANCER IN LAB ANIMALS.
Effects of Overexposure:EFFECTS OF OVEREXPOSURE MAY INCLUDE IRRIT OF
NOSE AND THROAT AND IRRIT OF THE DIGESTIVE TRACT. POTENTIAL HAZARD
TO THE KIDNEY AND LIVER. EYE:STINGING, WATERING, REDNESS.
SKIN:REDNESS, BURNING, DRYING, CRACKING, SKIN DAMAGE.
Medical Cond Aggravated by Exposure:CONDITIONS AGGRAVATED BY EXPOSURE
MAY INCLUDE SKIN DISORDERS, KIDNEY DISORDERS AND LIVER DISORDERS.

First Aid:EYE:MOVE TO FRESH AIR.FLUSH W/CLEAN WATER.IF SYMP PERSIST GET
MED ATTN.SKIN:IMMED REMOVE CONTAMIN CLOTH/SHOE/CONSTRICTIVE
JEWELRY.FLUSH AREA W/LG AMTS OF WATER.IF SKIN DAMAGE APPLY CLEAN
DRESSING.GET MED ATTN IMMED.IF NOT CLEANSE BY WASHING W/MILD SOAP
& WATER.IF IRRIT/REDNESS OCCURS GET MED ATTN.INHAL:MOVE TO FRESH
AIR.NOT BREATH GIVE ARAT RESP.BREATH DIFFI GIVE OXY.GET MED ATTN
IMMED.(SUPPLEMEN)

Flash Point Method:PMCC
Flash Point:125F,52C
Extinguishing Media:DRY CHEM,CO2(DISPLACES OXY),HALON(DECOMPOSE INTO
TOXIC MATL),FOAM.WATER SPRAY FOR COOL/PROTECT EXPOSED
MATL/STRUCTURE.
Fire Fighting Procedures:WEAR BUNKER GEAR & SCBA FOR FIRES BEYOND
INCIPIENT STAGE.ADD APPRO PROTECTIVE EQPMT AS WARRANT.ISOLATE
AREA.MOVE AWAY UNDAMAG CNTNRS.WATER SPRAY MIN/DISPERSE VA
Unusual Fire/Explosion Hazard:FLAMM.MYA BE IGNITED BY IGN SOURCES.VAP
TRAVEL LONG DISTANCES & IGN/BACKFLASH.CREATE VAP/AIR EXPLOSION
HAZ.CNTNR NOT COOL CAN EXPLODE BY HEAT.

Spill Release Procedures:FLAMM.KEEP ALL IGN SOURCES & HOT METAL
SURFACES AWAY.USE NONSPARKING TOOLS/EXPLOSIONPROOF EQPMT.STAY
UPWIND.STOP SPILL/RELEASE W/O RISK.WEAR APPROPRIATE PPE.PREVENT
FROM ENTERING ALL WATERWAYS.DIKE.MI N VAP W/FOAM.ABSORB
W/APPROPRIATE ABSORB MATL.

Handling and Storage Precautions:HANDLE EMPTY CNTNRS W/CARE DUE TO
RESIDUE.BOND/GROUND EQPMT WHEN TRANSFERRING MATL.USE EXPLOSIONPROOF
EQMPT.DON'T PRESS/CUT/WELD/ETC NEAR EMPTY CNTNR.
Other Precautions:ENTER CONFINED SPACES(TANK,PIT)IAW ASTMD-4276 &
29CFR1910.146.USE RESP W/CONCEN EXCEED TLV.CONSULT ANSIZ49.1 &
OTHER GOVT/INDUSTRIAL REFS PERTAINING TO CLEAN/REPAIR/WELD/OTHER
OPERATIONS ON TANKS HAVI NG MATL.STORE/USE IN COOL,DRY,VENT AREA.

Respiratory Protection:IS ADVISED WHEN CONCEN EXCEED ESPOSURE LIMITS.
DEPENDING ON AIRBORNE CONCEN USE RES/GAS MASK W/APPROPRIATE
CARTRIDGES & CANNISTERS (NIOSH APPROVED IF AVAILABLE) OR
SUPPLIED-AIR EQMPMT.
Ventilation:EXPLOSION PROOF VENTILATION TO ADQUATELY MAINTAIN AIRBORNE
CONCEN BELOW EXPOSURE LIMITS.
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:SAFETY GLASSES/GOGGLES.
Other Protective Equipment:EYEWASH,QUICK-DRENCH SHOWER FACILITIES.CLEAN
WELL SHOE/CONTAMIN CLOTHING PRIOR TO REUSE.IMPERVIOUS CLOTHING BE
WORN.
Work Hygienic Practices:WASH WELL AFTER HANDLING.DO NOT WEAR CONTAMIN
CLOTH/SHOE.USE GOOD PERSONAL HYGIENE PRACTICE.DON'T SMOKE IN AREA
OF MATL.
Supplemental Safety and Health
PER MSDS MATL HAS NOT BEEN ID AS CARCINOGEN BY NTP,IARC,OSHA.DIESEL
EXHAUST PROBABLE CANCER HAZ BASED ON LAB ANIMALS TEST & CARCINOGEN
BY IARC. MATL LISTED ON CA PROP 65. 1STAID:INGEST:DO NOT INDUCE V
OMIT OR GIVE ANYTHING BY MOUTH.DO NOT LEAVE UNATTENDED.GET MED
ATTN.

HCC:F4
Boiling Pt:B.P. Text:490F,254C
Vapor Density:>1
Spec Gravity:0.82-0.88
Evaporation Rate & Reference:<1. NBUAC=1
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:CLEAR TO YELLOW LIQUID, CHARACTERISTIC PETROLEUM.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID ALL POSSIBLE SOURCES OF IGNITON.
Hazardous Decomposition Products:COMBUST CAN YIELD MAJOR AMTS OF OXIDES
OF CARBON & MINOR AMTS OF OXIDES OF SULFUR & NITROGEN.

Waste Disposal Methods:SPILLS INTO WATERWAYS CALL 800-424-8802 NAT RESP
CNTR. EPA(CERCLA)RQ:NONE. DRAIN EMPTY CNTNRS COMPLETELY,PROPERLY
BUNGED,RETURENED TO SUPPLIER/DRUM RECONDITIONER. RINSATE MAY BE
RCRA HAZ WASTE. DISPOS E OF IAW STATE/LOCAL/FED REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.